RICERCA ITALIANA     

Programmi di ricerca simili:

• 1 - Processi chimici realizzati in presenza di campo elettromagnetico per una Chimica Sostenibile
• 2 - SINTESI E STEREOCONTROLLO DI MOLECOLE ORGANICHE MEDIANTE METODOLOGIE INNOVATIVE E DI INTERESSE APPLICATIVO
• 3 - Ingegnerizzazione e sviluppo di catalizzatori molecolari o nanostrutturati e strategie sintetiche sostenibili (alta selettività e resa) per la produzione di sistemi molecolari complessi da unità semplici ed eco-compatibili.
• 4 - CICLOADDIZIONI CON RIDOTTO IMPATTO AMBIENTALE PER LA SINTESI DI SOSTANZE DI INTERESSE BIOLOGICO
• 5 - Sintesi organiche ecosostenibili mediate da nuovi sistemi catalitici
• 6 - SINTESI E STEREOCONTROLLO DI MOLECOLE ORGANICHE PER LO SVILUPPO DI METODOLOGIE INNOVATIVE DI INTERESSE APPLICATIVO.
• 7 - ELETTROCATALISI ED ELETTROSINTESI
• 8 - Sintesi diretta di H2O2 e suo uso integrato in sistemi nanoconfinati
• 9 - ETEROCICLI NON AROMATICI IN PROCESSI STEREOCONTROLLATI
• 10 - Stereoselezione in Sintesi Organica. Metodologie ed Applicazioni.

Classificazione scientifico-disciplinare

• Area scientifico disciplinare: Scienze chimiche
  • CHIMICA ORGANICA
  • CHIMICA FARMACEUTICA
  • CHIMICA DELL'AMBIENTE E DEI BENI CULTURALI

Classificazione brevettuale

• CHEMISTRY; METALLURGY
  • ORGANIC CHEMISTRY (such compounds as the oxides, sulfides, or oxysulfides of carbon, cyanogen, phosgene, hydrocyanic acid or salts thereof C01; products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds C01B33/44; macromolecular compounds C08; dyes C09; fermentation products C12; fermentation or enzyme-using processes to synthesise a desired chemical compound or composition or to separate optical isomers from a racemic mixture C12P; production of organic compounds by electrolysis or electrophoresis C25B3/00, C25B7/00)
    • ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR (preparation of carboxylic acid esters by telomerisation C07C67/47; telomerisation C08F)

Classificazione geografica

• Regione: Umbria

Bibliografia

1. S. M. George, Ed., Issue dedicated to Heterogeneous Catalysis Chem. Rew. 1995, 95, 475- 788.
2. J. M. Thomas, C. R. Theocaris "Inclusion Compounds" Vol. 5, Eds. By J. L. Atwood J. E. D. Davies and D. D. Mac Nicol, Oxford University Press, Oxford 1991, Chap. 4.
3. P. Laszlo, "Catalysis of organic reactions by inorganic solids" Acc. Chem. Res. 1986, 19, 121-127
4. A. Cornelis P. Laszlo, "Molding clays into efficient catalysts" Synlett, 1994, 155-161
5. A. Clearfield, G. D. Smith, "Crystallography and structure of a-Zirconium bis (monohydrogen orthophosphate) monohydrate" J. Inorg. Chem.,1969, 8,431-436.
6. a) M. Curini, O. Rosati, E. Pisani, U. Costantino, "Heterogeneous Catalysis in Carbonyl Regeneration from Oximes, Semicarbazones, and Tosylhydrazones by Zirconium Sulfophenyl Phosphonate" Synlett, 1996, 333; b) M. Curini, M.C. Marcotullio, E. Pisani, O. Rosati, U. Costantino, "Heterogeneous Catalysis in Carbonyl Regeneration from 1,3-Dithiolanes and 1,3-Dithianes by Zirconium Sulfophenyl Phosphonate", Synlett, 1997, 769; c) M. Curini, F. Epifano, M. C. Marcotullio, O. Rosati, U. Costantino, "Zirconium Sulfophenyl Phosphonate as Heterogeneous Catalyst in Tetrahydropyranylation of Alcohols and Phenols", Tetrahedron Lett., 1998, 39, 8159; d) M. Curini, F. Epifano, M. C. Marcotullio, O. Rosati, U. Costantino, "Heterogeneous Catalysis In Trimethylsilylation Of Alcohols And Phenols By Zirconium Sulfophenyl Phosphonate", Synthetic Commun., 1999, 29, 541; e) M. Curini, F. Epifano, M. C. Marcotullio, O. Rosati, M. Rossi, "Potassium Exchanged Zirconium hydrogen Phosphate as heterogeneous Catalyst in Cyanosilylation of Carbonyl Compounds", Synlett, 1999, 315; f) M. Curini, F. Epifano, M. C. Marcotullio, O. Rosati, M. Rossi, A. Tsadjout, "Heterogeneous Catalysis in Acetylation of Alcohols and Phenols promoted by Zirconium Sulfophenyl Phosphonate", Synthetic. Commun., 2000, 30, 1319; g) M. Curini, F. Epifano, M. C. Marcotullio, O. Rosati, M. Rossi, A. Tsadjout, "Potassium Exchanged Layered Zirconium phosphate as Base Catalyst for the Desilylation of Phenols Silyl Ethers", Synthetic Commun., 2000, 30, 3181; h) M. Curini, F. Epifano, M.C. Marcotullio, O. Rosati, "An Efficient Procedure for the Preparation of Cyclic Ketals and Thioketals Catalyzed by Zirconium Sulfophenyl Phosphonate" Synlett, 2001, 7, 1182-118; i) M. Curini, F. Epifano, M.C. Marcotullio, O. Rosati, M. Nocchetti, "Preparation and deprotection of 1,1-diacetates (acylals) using zirconium sulfophenyl phosphonate as catalyst", Tetrahedon Lett., 2002, 43, 2709-2711; l)M. Curini, F. Epifano, M.C. Marcotullio, O. Rosati, "Zirconium Sulfophenyl Phosphonate as a Heterogeneous Catalyst in the Preparation of a-Amino Alcohols from Epoxides" Eur. J. Org. Chem., 2001, 4149-4152; m) U. Costantino. F. Marmottini, M. Curini, O. Rosati, "Metal exchanged layered zirconium hydrogen phosphate as base catalyst of the Michael reaction", Catalysis Letters, 1993, 22, 333; n) U. Costantino, M. Curini, F. Marmottini, O. Rosati, E. Pisani, "Potassium Exchanged Layered Zirconium Phosphate as Base Catalyst in the Synthesis of 2-Nitroalkanols", Chem. Lett., 1994, 2215; o) M. Curini, F. Epifano, M.C. Marcotullio, O. Rosati, A. Tsadjout, "Potassium exchanged layered zirconium phosphate as base catalyst in Knoevenagel condensation" Synthetic Commun, 2002, 32, 355-362; p) M. Curini, F. Montanari, O. Rosati, E. Lioy, R. Margarita "Layered zirconium phosphate and phosphonate as heterogeneous catalyst in the preparation of pyrroles", Tetrahedron Lett., 2003, 40, 3923-3925;
7. a) J.L. Luche, Synthetic Organic Sonochemistry, Plenum Press, New York, 1998; b) T.J. Mason, J.P. Lorimer, Applied Sonochemistry, Wiley VCH, 2002.
8. Ashokkumar, M.; Grieser, F. Ultrasound Assisted Chemical Processes, Rev. Chem. Eng. 1999, 15 41.
9. Suslick, K.S.; Price, G.J. Applications of Ultrasound to Materials Chemistry, Ann. Rev. Mater. Sci. 1999, 29, 295.
10. a) Mason, T.J.; Cintas, P. Sonochemistry, in: Handbook of Green Chemistry and Technology, Blackwell, 2002, pp. 372-396; b) Cintas, P.; Luche J.L. Green chemistry - The sonochemical approach Green Chem. 1999, 1 (3), 115.
11. Nuchter, M.; Ondruschka, B.; Bonrath, W.; Gum, A. Microwave assisted synthesis - a critical technology overview Green Chem. 2004, 6 (2), 128
12. Lidstrom, P.; Tierney, J.; Wathey, B.; Westman, J. Microwave Assisted Organic Synthesis - a Review Tetrahedron 2001, 57; b) Wilson, N.S.; Roth, G.P. Recent Trends In Microwave-Assisted Synthesis Curr. Opinion Drug Disc. & Develop. 2002, 5 (4), 620.
13. Letellier, M.; Budzinski, H. Microwave assisted extraction of organic compounds Analysis, 1999, 27, 259.
14. Vinatoru, M.; Toma, M.; Mason, T.J. Ultrasonically Assisted Extraction of Bioactive Principles from Plants and their Constituents, in: T.J. Mason (Ed.), Advances in Sonochemistry, vol. 5, JAI Press, 1999, 209.

Parole Chiave

CATALISI ETEROGENEA; SONOCHIMICA; MICROONDE; STEREO- E REGIOSELETTIVITÀ; DETERMINAZIONE STRUTTURALE